A self-healing Sn anode with an ultra-long cycle life for sodium-ion batteries
| Autor: | Icpyo Kim, Hyewon Yeo, Changhyeon Kim, Gyu-Bong Cho, Jou-Hyeon Ahn, Hyo-Jun Ahn, Jae-Pyoung Ahn, Huihun Kim, Milan K. Sadan |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Materials science
Renewable Energy Sustainability and the Environment Sodium Sintering chemistry.chemical_element 02 engineering and technology General Chemistry Electrolyte 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Anode Ion Chemical engineering chemistry Electrode General Materials Science 0210 nano-technology Faraday efficiency Separator (electricity) |
| Zdroj: | Journal of Materials Chemistry A. 6:22809-22818 |
| ISSN: | 2050-7496 2050-7488 |
| DOI: | 10.1039/c8ta09544b |
| Popis: | For a next-generation sodium battery to replace lithium ion batteries, it is essential to develop an anode with a long cycle life and high rate. Sn is considered to be an ideal candidate for the anode of sodium ion batteries. Here, we report a Sn anode that exhibits ultra-long-term cycle stability with a high capacity of 554 mA h g−1 at 10C-rate for 5000 cycles. The optimized cell configuration consists of 1,2-dimethoxyethane as the electrolyte, a double separator including a nanoporous membrane, and a Sn anode with MWCNT as a conductive additive. Its capacity retention reaches up to 99.8% and its coulombic efficiency is near 100% for 5000 cycles. Surprisingly, we have discovered that the Sn powder exhibits a self-healing phenomenon during cycling. Sn is initially pulverized into a nanometer-sized powder, and then forms a three-dimensional porous coral-like structure in which ligament-shaped micrometer-sized Sn particles are connected with a low coordination number by room temperature sintering. The coral-like structure is mechanically stable towards volume change and electrically connected. The self-healing structure and mechanism provide a direction for the design of other electrodes with alloying mechanisms. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|