Synthesis and structure of the complex of uranyl citraconate with urea

Autor:	Larisa B. Serezhkina, V. N. Serezhkin, S. A. Novikov, M. A. Kolotilina, M. S. Grigor’ev
Rok vydání:	2016
Předmět:	Citraconate Infrared spectroscopy 010402 general chemistry 010403 inorganic & nuclear chemistry Uranyl 01 natural sciences 0104 chemical sciences Ion Crystallography chemistry.chemical_compound chemistry Urea Physical and Theoretical Chemistry Single crystal
Zdroj:	Radiochemistry. 58:451-456
ISSN:	1608-3288 1066-3622
DOI:	10.1134/s1066362216050027
Popis:	Crystals of [UO2(C5H4O4)(urea)2], where C5H4O4 2– is citraconate ion, were prepared and studied by IR spectroscopy and single crystal X-ray diffraction. The structure of the crystals is formed by chains having the same composition as the compound as a whole and belonging to the crystal-chemical group AТ11M2 1 (A = UO2 2+, Т11 = C5H4O4 2–, M1 = urea) of uranyl complexes. Comparative analysis of nonvalent interactions in the structures of uranyl complexes with citraconate ions was performed by the method of molecular Voronoi–Dirichlet polyhedra.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::417bb111d85f492fba3dd920bb65b49d https://doi.org/10.1134/s1066362216050027 Zobrazit plný text záznamu Full text from SpringerLink