Rh(PPh3)3Cl/ionic liquid (molten salt) as a thermoregulated and recyclable catalytic system for hydrosilylation

Autor:	Guo Qiao Lai, Jia Jian Peng, Hui Wu, Ying Bai, Yuan Deng, Jia Yun Li, Hua Yu Qiu, Wei Hong Gao
Rok vydání:	2007
Předmět:	chemistry.chemical_classification Hydrosilylation Process Chemistry and Technology Inorganic chemistry Catalysis chemistry.chemical_compound chemistry Ionic liquid Pyridinium Physical and Theoretical Chemistry Molten salt Selectivity Alkyl
Zdroj:	Journal of Molecular Catalysis A: Chemical. 278:97-101
ISSN:	1381-1169
DOI:	10.1016/j.molcata.2007.08.030
Popis:	We have investigated the use of Rh(PPh3)3Cl/ionic liquid (molten salt) as a thermoregulated and recyclable catalytic system for hydrosilylation. It was found that both conversion and selectivity could be influenced by the alkyl chains attached to the pyridinium and imidazolium cations. The Rh(PPh3)3Cl/ionic liquid (molten salt) catalyst system combines the advantages of an ionic liquid with convenient product separation, whilst the catalyst system can be reused at least 10 times without noticeable decrease of activity and selectivity.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::41790701952bb88c2606a2634df44f04 https://doi.org/10.1016/j.molcata.2007.08.030 Zobrazit plný text záznamu Full Text from ScienceDirect