On the application of the associative mean spherical approximation to the ion-dipole model for electrolyte solutions
| Autor: | Ihor Protsykevich, Myroslav Holovko |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Physics
010304 chemical physics Ionic bonding Electrolyte Condensed Matter Physics 01 natural sciences Molecular physics Atomic and Molecular Physics and Optics Electronic Optical and Magnetic Materials Ion Solvent Dipole Algebraic equation 0103 physical sciences Materials Chemistry Physical and Theoretical Chemistry 010306 general physics Scaling Spectroscopy Energy (signal processing) |
| Zdroj: | Journal of Molecular Liquids. 270:46-51 |
| ISSN: | 0167-7322 |
| DOI: | 10.1016/j.molliq.2018.03.106 |
| Popis: | The solution of the associative mean spherical approximation for the ion-dipole model of an electrolyte solution is simplified and analyzed. It is shown that the description of this model can be reduced to a system of three coupled non-linear algebraic equations for ion-ion, ion-dipole and dipole-dipole energy parameters J0, b 1 0 and b2. A possibility of introducing ionic and dipolar scaling parameters ΓB and λ is discussed. Analytical expressions for the thermodynamic functions and solvent static dielectric permittivity are presented. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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