Effective Charges and Ionicity in Molten Salts
| Autor: | H. B. Kavanoz, M Silbert, Mehmet Yilmaz, Havva Gurbuz |
|---|---|
| Rok vydání: | 2002 |
| Předmět: |
Thallium halides
Inorganic chemistry Ionic bonding Halide Thermodynamics chemistry.chemical_element Charge (physics) Condensed Matter Physics Alkali metal Copper Effective nuclear charge Electronic Optical and Magnetic Materials Electronegativity chemistry.chemical_compound chemistry Materials Chemistry Physical and Theoretical Chemistry |
| Zdroj: | Physics and Chemistry of Liquids. 40:115-121 |
| ISSN: | 1029-0451 0031-9104 |
| Popis: | We have used experimental values of the entropies, near melting, of molten salts to calculate their effective charges by using a charge a spheres model in the Mean Spherical Approximation (MSA). We compare the values of the effective charges with the electronegativity differences for a number of 1:1 molten salts. We find a reasonable good correlation for the alkali halides, but no for the copper, silver and thallium halides, and we offer an explanation for these results. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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