Development of TiO2 and TiO2/Fe-based polymeric nanocomposites by single-step laser pyrolysis
| Autor: | M. Scarisoreanu, Rodica Alexandrescu, R. Birjega, Florian Dumitrache, Gabriel Prodan, I. Morjan, Claudiu Fleaca, I.P. Morjan, A. Barbut |
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| Rok vydání: | 2013 |
| Předmět: |
chemistry.chemical_classification
Materials science Nanostructure Nanocomposite General Physics and Astronomy Nanoparticle Surfaces and Interfaces General Chemistry Polymer Disiloxane Condensed Matter Physics Surfaces Coatings and Films Characterization (materials science) Matrix (chemical analysis) chemistry.chemical_compound chemistry Chemical engineering Polymer chemistry Methyl methacrylate |
| Zdroj: | Applied Surface Science. 278:305-312 |
| ISSN: | 0169-4332 |
| DOI: | 10.1016/j.apsusc.2012.12.094 |
| Popis: | Polymer-based nanocomposites provided with inorganic cores were simultaneously manufactured by the single-step laser pyrolysis. A comparative study was performed on two types of nanocomposites, starting from two different systems: TiO2/methyl methacrylate (MMA) and TiO2/Fe/hexamethyl disiloxane (HMDSO) polymer. The reactive mixture contained TiCl4 as Ti precursor and alternatively, Fe(CO)5 (in case of TiO2/Fe mixture). The analytical techniques used for the characterization indicate distinct morphologies for the obtained nanostructures. Polyhedral and almost spherical nanoparticles in a coalescent matrix and very rare individual core–shell particles are noticed for the TiO2/MMA nanocomposites. Instead, nanoparticles presenting core–shell structures were often present in the TiO2/Fe/HMDSO polymeric nanocomposites. |
| Databáze: | OpenAIRE |
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