Selective oxidation of organic sulfides to sulfoxides using sugar derived cis-dioxo molybdenum(vi ) complexes: kinetic and mechanistic studies
| Autor: | Vimal Kumar Madduluri, Ajay K. Sah, Noorullah Baig |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
chemistry.chemical_classification
Sulfide 010405 organic chemistry General Chemical Engineering chemistry.chemical_element Sulfoxide General Chemistry 010402 general chemistry Kinetic energy 01 natural sciences Medicinal chemistry High-performance liquid chromatography 0104 chemical sciences Catalysis chemistry.chemical_compound chemistry Molybdenum Organic chemistry Spectroscopy Single crystal |
| Zdroj: | RSC Advances. 6:28015-28022 |
| ISSN: | 2046-2069 |
| Popis: | Six Mo(VI) complexes of 4,6-O-ethylidene-β-D-glucopyranosylamine derived ligands have been used for the selective oxidation of five organic sulfides to corresponding sulfoxides. The structure of a new sulfide [(((2-(phenylthio)phenyl)imino)methyl)naphthalen-2-ol] (S5) and its corresponding sulfoxide (SO5) has been established using single crystal X-ray diffraction studies along with other routine analytical techniques. The yields of sulfoxides were calculated using HPLC and one of the catalysts was recycled five times without any appreciable loss in its activity. Kinetic studies on sulfoxide formation was performed on compound S5 using UV-visible spectroscopy, which suggested overall first order kinetics. A plausible mechanism for sulfide oxidation has been proposed based on our findings and previous literature reports. |
| Databáze: | OpenAIRE |
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