Novel zinc(II) coordination polymers (CPs) based on flexible aliphatic carboxylic acids and an N-donor ligand for fluorescence sensors
| Autor: | Ramida Rattanakram, Tanwawan Duangthongyou, Kittipong Chainok, Jiraporn Buasakun, Phakinee Srilaoong, Chadchalerm Raksakoon |
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| Rok vydání: | 2020 |
| Předmět: |
010405 organic chemistry
Ligand chemistry.chemical_element Zinc Crystal structure 010402 general chemistry 01 natural sciences 0104 chemical sciences Inorganic Chemistry Metal chemistry.chemical_compound Trigonal bipyramidal molecular geometry chemistry visual_art Polymer chemistry Materials Chemistry visual_art.visual_art_medium Formate Carboxylate Physical and Theoretical Chemistry Single crystal |
| Zdroj: | Inorganica Chimica Acta. 511:119839 |
| ISSN: | 0020-1693 |
| DOI: | 10.1016/j.ica.2020.119839 |
| Popis: | Two novel zinc (II) coordination polymers based on flexible aliphatic carboxylate ligands, succinate, and citrate, with 1,2-di(4-pyridyl)ethylene (dpe), namely, [Zn(succinate)(dpe)]0.1.5H2O (1), and [Zn2(citrate)(formate)(H2O)(dpe)].2H2O (2) were synthesized by the appropriate methods. The crystal structures were determined by single crystal X-ray diffraction. The coordination spheres around the Zn2+ ions in (1) and (2) were tetrahedral and trigonal bipyramidal, respectively. The fluorescence properties of the compounds showed emission bands at 362 and 369 nm (λex = 280 nm) for 1 and 2, respectively. Both compounds were used as nitroaromatic explosive and metal ion sensors. They selectively sensed 2,4-dinitrophenol and Fe(III) ions based on fluorescence quenching effects. |
| Databáze: | OpenAIRE |
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