The Conformation of Medium-Sized Organosilicon Heterocycles: First evidence for the existence of a boat-boat conformation in a 12H-dibenzo[d,g][1,3,2]dioxasilocin

Autor:	Günther Rist, Hermann Fuhrer, Frank H. Clarke, Stephen D. Pastor, Hans-Rudolf Meier, Shum Sai P
Rok vydání:	1993
Předmět:	Chemistry Organic Chemistry Cyclohexane conformation Solid-state Crystal structure Biochemistry Catalysis Inorganic Chemistry chemistry.chemical_compound Crystallography Drug Discovery X-ray crystallography Molecule Physical and Theoretical Chemistry Organosilicon
Zdroj:	Helvetica Chimica Acta. 76:1476-1480
ISSN:	1522-2675 0018-019X
DOI:	10.1002/hlca.19930760408
Popis:	X-Ray Crystal-structure analysis of 2,4,8,10-tetrakis(1,1-dimethylethyl)-6,6-dimethyl-12H-dibenzo[d,g][1,3,2]-dioxasilocin showed that its eight-membered organosilicon heterocycle adopts a boat-boat (BB) conformation in the solid state (Figs. 2 and 3).
Databáze:	OpenAIRE
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