Imidazole- and alkylamine-ligated iron(II,III) chlorin complexes as models for histidine and lysine coordination to iron in dihydroporphyrin-containing proteins: characterization with magnetic circular dichroism spectroscopy

Autor:	Chi K. Chang, David K. Cooper, Ann M. Huff, Kevin M. Smith, John H. Dawson
Rok vydání:	1993
Předmět:	Hemeprotein Magnetic circular dichroism Stereochemistry Inorganic Chemistry chemistry.chemical_compound chemistry Polymer chemistry Pyridine Chlorin polycyclic compounds Imidazole Molecule Physical and Theoretical Chemistry Spectroscopy Histidine
Zdroj:	Inorganic Chemistry. 32:1460-1466
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic00060a023
Popis:	An extensive series of five- and six-coordinate (1-methylimidazole)-, (1-butylamine)-, and (pyridine)iron(II, III) chlorin complexes are characterized for the first time with magnetic circular dichroism (MCD) spectroscopy. The chlorins (dihydroporphyrins) employed are octaethychlorin, mesochlorin, and methyl chlorin (2,2,4-trimethyldeuterochlorin, featuring a gem-dimethyl-substituted peripheral carbon).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::40b5b4f13d39047c484e4d66a947f33f https://doi.org/10.1021/ic00060a023 Zobrazit plný text záznamu