Synthesis, photophysical properties, and photochemical activity of the water-soluble dyad based on fullerene С60 and chlorin e6 derivatives
| Autor: | P. A. Mikhailov, A. Yu. Belik, O. I. Gushchina, Ekaterina A. Khakina, Olga A. Kraevaya, Oscar I. Koifman, N. S. Goryachev, Andrey F. Mironov, Yu. V. Romanenko, Alexander I. Kotelnikov, A. Yu. Rybkin, L. I. Usol’tseva, P. A. Troshin |
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| Rok vydání: | 2017 |
| Předmět: |
Fullerene
Absorption spectroscopy 010405 organic chemistry Chemistry 010402 general chemistry Photochemistry 01 natural sciences Physics::Geophysics 0104 chemical sciences chemistry.chemical_compound Electron transfer Covalent bond Excited state Chlorin polycyclic compounds Physics::Atomic and Molecular Clusters Moiety Singlet state Physics::Chemical Physics Physical and Theoretical Chemistry Astrophysics::Galaxy Astrophysics |
| Zdroj: | Doklady Physical Chemistry. 477:222-226 |
| ISSN: | 1608-3121 0012-5016 |
| DOI: | 10.1134/s0012501617120065 |
| Popis: | Chlorin e6 derivative and water-soluble dyad resulting from covalent bonding of polyanionic fullerene С60 derivative to chlorin e6 derivative were synthesized and studied for spectral properties and photochemical activity. A considerable change in the absorption spectra and pronounced fluorescence quenching for the chlorin moiety included in the dyad were identified. The singlet excited state of chlorin is quenched via electron transfer from the excited chlorin to the fullerene core. A comparison of the photochemical activities of the test compounds in aqueous solutions showed a tenfold increase in the photochemical activity of the chlorin–fullerene dyad compared with free chlorin per absorbed light quantum. |
| Databáze: | OpenAIRE |
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