An Expeditious Route to 3β,14β-Dihydroxy-5β-androstane-17β-carboxaldehyde

Autor:	Mauro Gobbini, Marco Torri
Rok vydání:	1997
Předmět:	chemistry.chemical_classification Chemistry Organic Chemistry Oxidative cleavage Combinatorial chemistry Lactone Catalysis
Zdroj:	Synthetic Communications. 27:1115-1122
ISSN:	1532-2432 0039-7911
DOI:	10.1080/00397919708003058
Popis:	An efficient and practical synthesis of 3β,14β-dihydroxy-5β-androstane-17β-carboxaldehyde is described. The key oxidative cleavage of the unsaturated lactone of 3-acetyldigitoxigenin 1 utilises RuO4 as catalytic and NaIO4 as stoichiometric oxidants.
Databáze:	OpenAIRE
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