Hydrogen peroxide as an oxidant in starch oxidation using molybdovanadophosphate for producing a high carboxylic content

Autor:	Yalinu Poya, Xiaoli Chen, Junyou Shi, Hang Wang, Xiaohong Wang, Ting Jia
Rok vydání:	2015
Předmět:	inorganic chemicals chemistry.chemical_compound chemistry Starch General Chemical Engineering Oxidizing agent food and beverages Organic chemistry General Chemistry Hydrogen peroxide Catalysis
Zdroj:	RSC Advances. 5:45725-45730
ISSN:	2046-2069
DOI:	10.1039/c5ra07747h
Popis:	(NH4)5H6PV8Mo4O40 is an improved bi-functional catalyst that has been used for oxidizing starch by hydrogen peroxide. The effects of oxidation with hydrogen peroxide on the carboxyl content were studied systematically to produce high polyhydroxycarboxylic acids even when using very low amounts of the catalyst. (NH4)5H6PV8Mo4O40 exhibited the best catalytic performance with a carboxylic content of 0.648 mol per 100 g, which could be attributed to the synergy of its Bronsted acidity and strong efficient oxidant center. This catalyst can perform controllable starch oxidation and can be recycled for reuse.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::408a5c1bdf443cddd444757325b9e7f8 https://doi.org/10.1039/c5ra07747h Zobrazit plný text záznamu