The influence of nanoparticles on hydrodynamic characteristics and mass transfer performance in a pulsed liquid–liquid extraction column
Autor: | Mohammad Reza Mozdianfard, Hossein Bahmanyar, Nafiseh Khoobi, Amir Bahmanyar |
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Rok vydání: | 2011 |
Předmět: |
Materials science
Process Chemistry and Technology General Chemical Engineering Mass flow Sonication Extraction (chemistry) Analytical chemistry Energy Engineering and Power Technology Nanoparticle General Chemistry Industrial and Manufacturing Engineering Nanofluid Liquid–liquid extraction Mass transfer Phase (matter) |
Zdroj: | Chemical Engineering and Processing: Process Intensification. 50:1198-1206 |
ISSN: | 0255-2701 |
DOI: | 10.1016/j.cep.2011.08.008 |
Popis: | With respect to the influence of nanoparticles on mass transfer characteristics, limited number of studies available in the literature, deal primarily with gas–liquid systems. In this work, mass transfer performance and hydrodynamic characteristics including static and dynamic dispersed phase hold-ups of nanofluids have been investigated for pulsed liquid–liquid extraction column (PLLEC). The nanofluids used were prepared by dispersing SiO 2 nanoparticles of 0.01, 0.05 and 0.1 volume percent with two different hydrophobicities in kerosene as base fluid using ultrasonication. UV–vis spectrophotometer was also used for evaluation of the nanofluids stability. The results were compared with conditions of no-nanoparticles in the dispersed phase and in the absence of mass transfer effect (no acetic acid as solute). Different pulsation intensities were maintained for the fixed mass flow rates of dispersed ( Q d ) and continuous ( Q c ) phases (with ratio Q c / Q d = 1.2) with mass transfer direction being made from the dispersed phase to the continuous one. The results indicate that in the presence of the nanofluids, static and dynamic dispersed phase hold-ups increased by 23–398%, and 23–257%, respectively, while mass transfer performance was enhanced by 4–60%. |
Databáze: | OpenAIRE |
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