Synthesis and Structural Elucidation of Ni(II), Cu(II), Zn(II) and Cd(II) Metal Complexes of Oxazoline Based Ligands

Autor:	Bitew Kassaw Dessie, Muluye Melak Zenebe, Atnafu Guadie Assefa
Rok vydání:	2015
Předmět:	Molar concentration General Engineering Infrared spectroscopy Conductance Tetrahedral molecular geometry Oxazoline Magnetic susceptibility Metal chemistry.chemical_compound Crystallography chemistry visual_art visual_art.visual_art_medium Heteronuclear single quantum coherence spectroscopy
Zdroj:	American Journal of Applied Chemistry. 3:40
ISSN:	2330-8753
DOI:	10.11648/j.ajac.20150302.12
Popis:	Synthesis of 2-(2'-hydroxyphenyl)-2-oxazoline(2-Phox) and 2-(4-hydroxyphenyl)-2-oxazoline(4-Phox) and their complexes with Ni(II), Cu(II), Zn(II) and Cd(II) have been done. They have been characterized by elemental analysis, magnetic susceptibility, NMR (HH-COSY, HSQC, HMBC), UV-vis, IR spectroscopy and conductance measurement. The complexes were formed in 1:2 (M:L) ratio. Their molar conductance of one millimolar solution measured in DMF indicated them to be non electrolyte. On the basis of these studies a tetrahedral geometry has been assigned for all the complexes.
Databáze:	OpenAIRE
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