Popis: |
High-resolution records for carbon isotopes of organic matter and n-alkane compounds were investigated in two gravity cores (SJP15-2 and SJP15-4) taken from the southern continental shelf of the Korean peninsula to evaluate the influxes of terrestrial biomarkers and their linkage to paleoclimate and marine environmental changes since the last 4 kyr. The total organic carbon contents were < 1%, and the carbon isotope ratio of organic matters (d13Corg) ranged from approximately −21‰ to -22‰ and, they did not highly fluctuate throughout the two cores. However, the vertical distributions of total terrestrial biomarkers, long-chain n-alkanes (nC25-35), and individual n-alkane compounds exhibited distinctive fluctuations. There are two switching points that discriminate patterns of excursion and distribution at ca. 2.5 ka, and 0.5 ka. Several n-alkane combined indices such as average chain length (ACL), carbon preference index (CPI), and paleovegetation index (Paq) were coincident with these switching points, implying that the supply of terrestrial biomarkers was strongly associated with environmental changes at the source area. In particular, variations of compound-specific n-alkanes isotope and the ratios of nC31/nC27 and nC31/nC29 follow those of n-alkanes indices, implying that this millennium records were associated with wetter climate conditions, and thus paleovegetation and paleoclimate variation. Comparison with previous data of the detrital quartz from the East China Sea and aeolian dust in the Cheju (Jeju) Island, South Korea, and Dongge cave oxygen isotope records indicates strong synchronicity with gradual paleoclimate degradation between 2.5 ka and 0.5 ka. Therefore, our high-resolution n-alkane data are very useful for reconstructing past climatic variability, suggesting that paleoclimate system of the East Asian region may have influenced the sediment records of study area since the last 4 kyr. |