Tetrakisdehydro[16]annuleno[18]annulene
Autor: | Tsutomu Nakagawa, Koichi Sakano, Masahiko Iyoda, Masazumi Nakagawa |
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Rok vydání: | 1981 |
Předmět: | |
Zdroj: | Tetrahedron Letters. 22:2655-2658 |
ISSN: | 0040-4039 |
Popis: | Tetrakisdehydro[16]annuleno consisting of trisdehydro[16]annulene and bisdehydro[18] annulene has been synthesized. Induction of para- and diamagnetic ring currents in 16- and 18-membered rings, respectively, was clearly recognized by the 1H NMR spectroscopy. A marked suppresion of the diatropicity in the 18π moiety was observed in the same trend as observed in tetrakisdehydro[14]annuleno[16]annulene. |
Databáze: | OpenAIRE |
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