Tetrakisdehydro[16]annuleno[18]annulene

Autor: Tsutomu Nakagawa, Koichi Sakano, Masahiko Iyoda, Masazumi Nakagawa
Rok vydání: 1981
Předmět:
Zdroj: Tetrahedron Letters. 22:2655-2658
ISSN: 0040-4039
Popis: Tetrakisdehydro[16]annuleno consisting of trisdehydro[16]annulene and bisdehydro[18] annulene has been synthesized. Induction of para- and diamagnetic ring currents in 16- and 18-membered rings, respectively, was clearly recognized by the 1H NMR spectroscopy. A marked suppresion of the diatropicity in the 18π moiety was observed in the same trend as observed in tetrakisdehydro[14]annuleno[16]annulene.
Databáze: OpenAIRE