Synthesis and crystal structure of the sodium complex with 2-(diphenylacetyl)indandione-1,3

Autor:	K. K. Palkina, A. N. Kochetov, V. S. Sergienko, Andrei V. Churakov
Rok vydání:	2011
Předmět:	Inorganic Chemistry Crystallography Chemistry Ligand Group (periodic table) Hydrogen bond Materials Science (miscellaneous) Atom Crystal structure Sodium complex Physical and Theoretical Chemistry Conjugated system Monoclinic crystal system
Zdroj:	Russian Journal of Inorganic Chemistry. 56:1258-1263
ISSN:	1531-8613 0036-0236
DOI:	10.1134/s0036023611080201
Popis:	The sodium complex with 2-(diphenylacetyl)indandione-1,3 (HL) have been synthesized and studied by X-ray diffraction analysis. Crystals of [Na4(H2O)4L4] (I) precipitated from aqueous acetone are monoclinic, Z = 2, space group P21/c, a = 12.171(1) A, b = 10.527(1) A, c = 29.777(2) A, β = 97.455(1)°. The structure of compound I is based on a centrosymmetric tetranuclear [Na4O12] cage. Two central Na(2) atoms are coordinated to four O atoms of two L ligands. The central and peripheral atom polyhedrons [Na(2)O6] and [Na(1)O5] are joined by a common edge formed by two O atoms of two L ligands. Tetranuclear moieties are joined into the framework by hydrogen bonds, numerous C-H-π contacts, and π-π stacking-contacts between the conjugated and aromatic ligand systems of neighboring tetramers.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::4066e23d9c4744be5437e2aed49ec8f8 https://doi.org/10.1134/s0036023611080201 Zobrazit plný text záznamu Full text from SpringerLink