Polymer-supported catalysts in nucleophilic addition of n-butanol to isocyanates

Autor:	R.P. Tiger, M.A. Levina, S.G. Entelis, P. A. Berlin
Rok vydání:	1991
Předmět:	Steric effects chemistry.chemical_compound Nucleophilic addition Chemistry n-Butanol Polymer chemistry Kinetics General Engineering Organic chemistry Alcohol Isocyanate Polymer supported Catalysis
Zdroj:	Journal of Molecular Catalysis. 64:15-22
ISSN:	0304-5102
DOI:	10.1016/0304-5102(91)85124-k
Popis:	The kinetics of n-butanol addition to isocyanate in the presence of organotin compounds and their polymer-supported analogues has been investigated. The functionalized polymer chain creates steric hindrances to the formation of non-reactive complexes which include organotin sites. The catalytic activity increases by a factor of 10–100 as compared with low molecular weight analogues.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::404b581ae3a1e1f96bdc3de89196b043 https://doi.org/10.1016/0304-5102(91)85124-k Zobrazit plný text záznamu