Absolute configuration of a chiral proton sponge

Autor:	Gulnara K. Kadorkina, Remir G. Kostyanovsky, Yulia V. Nelyubina, Alexander F. Pozharskii, Orudzh G. Nabiev, Ivan I. Chervin, Konstantin A. Lyssenko, Alexander V. Degtyarev
Rok vydání:	2008
Předmět:	Sponge chemistry.chemical_compound Crystallography Proton biology Chemistry Stereochemistry Resolution (electron density) Absolute configuration General Chemistry Enantiomer biology.organism_classification Naphthalene
Zdroj:	Mendeleev Communications. 18:86-87
ISSN:	0959-9436
DOI:	10.1016/j.mencom.2008.03.011
Popis:	By the spontaneous resolution of racemic compound 1,8-bis(dimethylamino)-2-(α-hydroxy-α-phenylethyl)naphthalene (±)-1, enantiomer (–)-1 was obtained; its treatment with C5H5N·HBr resulted in the formation of proton sponge (–)-2; the absolute configurations of (R)-(–)-2 and, as a consequence, (R)-(–)-1 were determined by XRD analysis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::402f15e0d3d75111a0673b37eb56d2ab https://doi.org/10.1016/j.mencom.2008.03.011 Zobrazit plný text záznamu Full Text from ScienceDirect