The structure of a fluid mixture of deuterated ethane and deuterated methane by high-pressure neutron diffraction experiments
| Autor: | Klaus Tödheide, Till Pfleiderer, Henry E. Fischer, Helmut Bertagnolli |
|---|---|
| Rok vydání: | 2001 |
| Předmět: |
Quantitative Biology::Biomolecules
Chemical substance Monte Carlo method Intermolecular force Neutron diffraction Analytical chemistry General Physics and Astronomy Supercritical fluid Methane law.invention chemistry.chemical_compound Deuterium chemistry Magazine law Astrophysics::Earth and Planetary Astrophysics Physics::Chemical Physics Physical and Theoretical Chemistry |
| Zdroj: | The Journal of Chemical Physics. 115:5561-5566 |
| ISSN: | 1089-7690 0021-9606 |
| DOI: | 10.1063/1.1396847 |
| Popis: | High-pressure neutron diffraction data on a mixture of 33.3 mole % deuterated ethane and 66.7 mole % deuterated methane at six supercritical states are presented. The density could be varied by a factor larger than 2. The density dependence of the intra- and intermolecular structure is determined. The resulting total atomic pair correlation functions are compared with the results of Monte Carlo computer simulations with effective pair potentials. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|