Tungsten pentacarbonyl complexes of 1,3-benzoxaphospholes
| Autor: | Curtis E. Moore, John D. Protasiewicz, Sloane Evariste, Arnold L. Rheingold, Alexandra B. Grimm |
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| Rok vydání: | 2017 |
| Předmět: |
010405 organic chemistry
Chemistry Stereochemistry Organic Chemistry chemistry.chemical_element Crystal structure Nuclear magnetic resonance spectroscopy Tungsten Conjugated system 010402 general chemistry 01 natural sciences Biochemistry Fluorescence 0104 chemical sciences Inorganic Chemistry Crystallography Materials Chemistry Moiety Physical and Theoretical Chemistry Single crystal |
| Zdroj: | Journal of Organometallic Chemistry. 851:9-13 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/j.jorganchem.2017.08.021 |
| Popis: | 2-R-1,3-Benzoxaphospholes (R-BOPs) are examples of fluorescent conjugated materials possessing low coordinate phosphorus centers. A series of 2-(p-XC6H4)-BOPs (X = H, Cl, Br, Me, OMe) react with [W(CO)5(NCMe)] to produce the crystalline complexes [W(CO)5(2-Ar-BOP)] (2a-e). All complexes were characterized by NMR spectroscopy and by single crystal X-ray diffraction. The crystal structures all displayed extensive π-stacking of the BOP ligands and gear locking of the CO groups. Addition of the protecting [W(CO)5] group to the BOPs was discovered to significantly diminish fluorescence of the BOP moiety. |
| Databáze: | OpenAIRE |
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