Synthesis and Characterization of Li(Li0.05Ni0.6Fe0.1Mn0.25)O2 Cathode Material for Lithim Ion Batteries

Autor: A. Nichelson, S. Karthickprabhu, K. Karuppasamy, Edgar Valenzuela, X. Sahaya Shajan, Thaiyan Mahalingam, S. Thanikaikarasan
Rok vydání: 2018
Předmět:
Zdroj: Journal of New Materials for Electrochemical Systems. 21:051-056
ISSN: 2292-1168
1480-2422
Popis: A new type of lithium enriched cathode material Li (Li0.05Ni0.6Fe0.1Mn0.25)O2 was synthesized by sol-gel method with citric acid as a chelating agent. The structural and morphological studies were systematically investigated through X-ray diffraction, SEM with EDS, FT-IR and Raman analyses. The crystallite size of the Li (Li0.05Ni0.6Fe0.1Mn0.25)O2 cathode material was found to be 45 nm thereby leads to the feasible movement of lithium ion all through the material. FT-IR spectroscopy was used to confirm the metal-oxygen interaction in the prepared cathode material. The electrical properties of the Li (Li0.05Ni0.6Fe0.1Mn0.25)O2 cathode material were studied by impedance and dielectric spectral analyzes. Li (Li0.05Ni0.6Fe0.1Mn0.25)O2 showed a maximum ionic conductivity of 10-6 S/cm at ambient temperature.
Databáze: OpenAIRE