The melding of dithiocarbamate and alkyne moieties at molybdenum centres; new ligands and heterometallacyclic complexes

Autor: Charles G. Young, Xue F. Yan, Edward R. T. Tiekink, Bronwyn Fox
Rok vydání: 1994
Předmět:
Zdroj: Journal of the Chemical Society, Chemical Communications. :2579
ISSN: 0022-4936
DOI: 10.1039/c39940002579
Popis: The reactions of [Mo2(µ-S2)2(S2CNEt2)4](BF4)2 and MoO(S2)(S2CNR2)2 with dimethyl acetylenedicarboxylate result in the formation of orange and green heterometallacyclic complexes containing the novel organosulfur 2-sulfanylethylthiomethylidene (N,N-dialkyl) ammoniumato-C,S,S′ and 2,3-µ-1,3-disulfanylprop-2-enylidene (N,N-dialkyl)-ammoniumato-S,S′ ligands.
Databáze: OpenAIRE