The melding of dithiocarbamate and alkyne moieties at molybdenum centres; new ligands and heterometallacyclic complexes
Autor: | Charles G. Young, Xue F. Yan, Edward R. T. Tiekink, Bronwyn Fox |
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Rok vydání: | 1994 |
Předmět: | |
Zdroj: | Journal of the Chemical Society, Chemical Communications. :2579 |
ISSN: | 0022-4936 |
DOI: | 10.1039/c39940002579 |
Popis: | The reactions of [Mo2(µ-S2)2(S2CNEt2)4](BF4)2 and MoO(S2)(S2CNR2)2 with dimethyl acetylenedicarboxylate result in the formation of orange and green heterometallacyclic complexes containing the novel organosulfur 2-sulfanylethylthiomethylidene (N,N-dialkyl) ammoniumato-C,S,S′ and 2,3-µ-1,3-disulfanylprop-2-enylidene (N,N-dialkyl)-ammoniumato-S,S′ ligands. |
Databáze: | OpenAIRE |
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