An Efficient, Simple and Inexpensive Method for the Preparation of 1,4-Benzoquinone MonoketalsviaAnodic Oxidation of 1,4-Dimethoxybenzenes

Autor:	Richard J. K. Taylor, Lewis Norman John, Elisabeth C. L. Gautier, Alexander McKillop
Rok vydání:	1994
Předmět:	1 4-Benzoquinone chemistry.chemical_compound chemistry Simple (abstract algebra) Yield (chemistry) Anodic oxidation Organic Chemistry Inorganic chemistry
Zdroj:	Synthetic Communications. 24:2989-3008
ISSN:	1532-2432 0039-7911
DOI:	10.1080/00397919408010619
Popis:	Anodic oxidation of a series of 1-substituted-2,5-dimethoxybenzenes gives 2-substituted-1,1,4,4-tetramethoxycyclohexa-2,5-dienes in almost quantitative crude yield. Selective monohydrolysis of these bis-ketals is possible in many cases, and gives 3-substituted-4,4-dimethoxycyclohexa-2,5-dienones in good to excellent overall yield.
Databáze:	OpenAIRE
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