Structural characterization and luminescence behavior of a 2D silver (I) coordination polymer assembled from pyridine-2,6-dicarboxylic acid N-oxide

Autor: Wei-Ping Wu, Ya-Pan Wu, Yao-Yu Wang, Ping Liu, Qi-Zhen Shi, Cui-Juan Wang
Rok vydání: 2006
Předmět:
Zdroj: Inorganic Chemistry Communications. 9:645-648
ISSN: 1387-7003
Popis: A 2D network complex [Ag2(pydco)]n (1) (pydco = pyridine-2,6-dicarboxylic acid N-oxide) was synthesized and structurally characterized. Fluorescence spectrum of complex 1 and the free ligand indicates that the cooperative association of Ag–Ag contacts and the intraligand (π–π∗) interactions lead to the unusual intense fluorescent emission upon photoexcitation.
Databáze: OpenAIRE