The electrical resistivity and super-conductivity of some uranium alloys and compounds

Autor: John K. Hulm, B.S. Chandrasekhar
Rok vydání: 1958
Předmět:
Zdroj: Journal of Physics and Chemistry of Solids. 7:259-267
ISSN: 0022-3697
Popis: The electrical resistivity and superconductivity of a series of a (orthorhombic) and quenched y (body-centered cubic) binary alloys of uranium with niobium and molybdenum were investigated at temperatures down to 1 °K. Anomalous resistivity behavior occurs in both types of structure. The γ-alloys are particularly unusual in possessing a negative temperature coefficient from room temperature down to the superconducting transition point. Both systems exhibit superconducting transitions, the γ-alloys in the vicinity of 2°K and the α-alloys closer to 1°K. Some success was achieved in a qualitative interpretation of the resistive and superconductive properties of the alloys in terms of a hypothetical band structure of uranium. Ten intermetallic compounds of uranium were also tested for superconductivity down to about 1°K. Four new superconductors were discovered: UCo (1.70°K), U 6 Mn (2.32°K), U 6 Fe (3.86°K) and U 6 Co (2.29°K). The last three compounds are isomorphous and include the first superconducting compounds of manganese and iron.
Databáze: OpenAIRE