Basicity and structure of 5-hydroxybenzimidazoles in nitromethane

Autor:	B. A. Korolev, L. A. Osmolovskaya, Yu. V. Kuznetsov, L. D. Smirnov, L. G. Stolyarova
Rok vydání:	1992
Předmět:	chemistry.chemical_compound chemistry Nitromethane Automotive Engineering chemistry.chemical_element General Chemistry Photochemistry Nitrogen Inductive effect
Zdroj:	Bulletin of the Russian Academy of Sciences Division of Chemical Science. 41:333-336
ISSN:	1573-9171 1063-5211
DOI:	10.1007/bf00869526
Popis:	Examination of the acid-base properties of 5-hydroxybenzimidazoles has shown them to exist in nitromethane as the 5-hydroxy-tautomers. Substituents in the 2-position have a predominantly inductive effect on the basicity of the 3-nitrogen, rationalized as in other nitrogen heterocycles by the proximity of the substituents to the reaction center.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3fc015975ba9c039b6ad3c09c169fe90 https://doi.org/10.1007/bf00869526 Zobrazit plný text záznamu Full text from SpringerLink