Electrosynthesis and studies of adducts of 2-amino-1-methylbenzimidazole with metal chelates based on 2-tosylamino-N-salicylideneaniline

Autor: A. S. Antsyskkina, A. S. Burlov, G. G. Sadikov, D. A. Garnovskii, Igor S. Vasilchenko, A. D. Garnovskii, A. Sousa, S. G. Sigeikin, Alfonso Castiñeiras
Rok vydání: 1996
Předmět:
Zdroj: Russian Chemical Bulletin. 45:1988-1992
ISSN: 1573-9171
1066-5285
DOI: 10.1007/bf01457793
Popis: For the first time the adducts of 2-amino-I-methylbenzimidazole (L) with cobalt, copper, and zinc chelates based on 2-tosylamino-N-salicylideneaniline were electrochemically synthesized, and the properties and structures of these adducts were studied. According to the IR and1H NMR spectral data on the adducts obtained and X-ray structural analysis of the copper complex, the adducts of composition mL · ML' · nH2O (m = 1 or 2; n = 0, 1, or 2) contain the L moiety bonded to the metal atom through the pyridine-type N atom of the imidazole ring.
Databáze: OpenAIRE