Self-Assembly of Interlocked Structures: Rotaxanes, Polyrotaxanes and Molecular Necklaces

Autor:	Jungseok Heo, Dongmok Whang, You-Moon Jeon, Soo-Gyun Roh, Kimoon Kim, Ki-Min Park
Rok vydání:	1999
Předmět:	chemistry.chemical_classification Materials science Rotaxane Nanostructure chemistry Cucurbituril Metal ions in aqueous solution Supramolecular chemistry Molecule Nanotechnology Self-assembly Condensed Matter Physics Coordination complex
Zdroj:	Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals. 327:65-70
ISSN:	1058-725X
DOI:	10.1080/10587259908026782
Popis:	Our recent work on construction of interlocked structures such as rotaxanes, polyrotaxanes and molecular necklaces using the principles of self assembly and coordination chemistry is described. In the synthesis of these structures, the barrel-shape molecule cucurbituril is used as a molecular “bead” and metal ions or metal complexes are used as “glue” or “angle connectors”. Judicious choice of metal ions, counter ions and “strings” is important in order to construct the desired supramolecular structures.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3f9b6098dbbddf2fc4113d7ceb2abc75 https://doi.org/10.1080/10587259908026782 Zobrazit plný text záznamu