Investigation of condensed heteroaromatic systems including a thiophene ring

Autor:	D. D. Gverdtsiteli, V. A. Ferapontov, V. P. Litvinov, E. G. Ostapenko
Rok vydání:	1973
Předmět:	chemistry.chemical_compound chemistry Column temperature Elution Organic Chemistry Thiophene Molecule Organic chemistry Ring (chemistry) Retention time Medicinal chemistry Flue-gas desulfurization
Zdroj:	Chemistry of Heterocyclic Compounds. 9:173-179
ISSN:	1573-8353 0009-3122
DOI:	10.1007/bf00569155
Popis:	A method for the gas-chromatographic analysis of high-boiling polycondensed heteroaromatic compounds with a thiophene ring (CHC) containing up to five condensed rings was developed. The optimum analysis conditions were found, the retention times were determined, and the dependence of the elution characteristics on the column temperature and CHC structure was followed. Elution occurs in conformity with the number of rings in the CHC molecule, and compounds with the same number of rings (with allowance for substituents with a benzenering) are arranged in sufficiently isolated groups. The phenomenon of inversion of the retention volumes of some CHC as the temperature rises was noted. A method for the indirect analysis of CHC by chromatography of the products of desulfurization of them was developed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3f981d9e1b05c22ad5c35d87facee893 https://doi.org/10.1007/bf00569155 Zobrazit plný text záznamu Full text from SpringerLink