Calculation of the main characteristics of polymer branching taking into account the exchange of activity between polymerization centres

Autor:	V V Bronskaya, E V Garifullina, T V Ignashina, G A Aminova, G V Manuyko, O S Kharitonova, D S Balzamov
Rok vydání:	2022
Zdroj:	IOP Conference Series: Earth and Environmental Science. 981:042023
ISSN:	1755-1315 1755-1307
DOI:	10.1088/1755-1315/981/4/042023
Popis:	The calculation of the main characteristics of the branching of the polymer is presented in the article using the example of polymerization of butadiene in the presence of an organolithium catalytic system modified with polyfunctional sodium and magnesium alcoholates. The addition of a modifier to the catalytic system leads to the participation in the polymerization of at least two types of active centers, which is the reason for some branching of macromolecules. The complemented mathematical model of the periodic process, taking into account the exchange of activity between the two centers, allows to calculate the main characteristics of branching.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3f5dbf09bdfdb7c1da0c2b15855c171d https://doi.org/10.1088/1755-1315/981/4/042023 Zobrazit plný text záznamu