Rotational effects in low energy dissociative recombination of diatomic ions

Autor:	M. Raoult, A. Suzor-Weiner, Ioan F. Schneider, C. Strömholm, Mats Larsson, B. Vâlcu
Rok vydání:	1998
Předmět:	Physics Optical physics Molecular physics Diatomic molecule Atomic and Molecular Physics and Optics Ion symbols.namesake Rydberg formula symbols Molecule Physics::Chemical Physics Atomic physics Dissociative recombination Recombination Direct process
Zdroj:	The European Physical Journal D - Atomic, Molecular and Optical Physics. 1:71-78
ISSN:	1434-6079 1434-6060
DOI:	10.1007/s100530050065
Popis:	The effect of rotational interaction in the low energy dissociative recombination process of diatomic molecules has been explored for typical molecular ions ( ) which sample a large range of molecular masses. We show that rotation plays a role mainly for the indirect recombination process through bound Rydberg states, and for light molecules. When the direct process based on a strong electronic interaction is fast and dominating, rotational couplings can be safely neglected especially for heavier molecules like NO.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3f53357cd88bd2a2ebd0537695d20e19 https://doi.org/10.1007/s100530050065 Zobrazit plný text záznamu Full text from SpringerLink