Eco-friendly sodium bicarbonate treatment and its effect on epoxy and polyester coir fibre composites
| Autor: | Júlio Cesar dos Santos, Valdir Mano, Lívia Ávila de Oliveira, Rodrigo Teixeira Santos Freire, Túlio Hallak Panzera, Luciano Machado Gomes Vieira |
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| Rok vydání: | 2019 |
| Předmět: |
Thermogravimetric analysis
Materials science Flexural modulus 0211 other engineering and technologies 020101 civil engineering 02 engineering and technology Building and Construction Epoxy 0201 civil engineering Polyester Flexural strength visual_art 021105 building & construction Ultimate tensile strength visual_art.visual_art_medium General Materials Science Coir Composite material Elastic modulus Civil and Structural Engineering |
| Zdroj: | Construction and Building Materials. 211:427-436 |
| ISSN: | 0950-0618 |
| DOI: | 10.1016/j.conbuildmat.2019.03.284 |
| Popis: | This work evaluates a new eco-friendly surface treatment method for coir fibres based on sodium bicarbonate (NaHCO3). The fibres are treated with 10 wt% NaHCO3 solution for different periods of time (24, 96 and 168 h). A 2141 Full Factorial Design is established to investigate the effect of the type of matrix (epoxy and polyester) and treatment time (24, 96 and 168 h) on the mechanical properties of coir fibre composites. X-Ray diffraction (XRD) analysis reveals that the treatment does not promote a complete change of cellulose-I into cellulose-II. However, the degradation of hemicellulose and pectin of the fibre surface is evidenced by the thermogravimetric (TGA) curves. The chemical treatment contributes to increase the fibre density and to reduce its thermal stability. Single fibre tensile tests reveal a gradual increase in the elastic modulus attributed to the treatment time factor. Epoxy composites presented higher tensile and flexural strength in comparison to polyester composites, which exhibit higher tensile and flexural modulus. The alkaline treatment does not affect the mechanical strength of the composites. However, higher tensile and flexural moduli are obtained when the treatment time increases to 96 or 168 h. The proposed treatment proves to be feasible and efficient to increase the stiffness of coir fibre composites, besides being less damaging to the environment after disposal when compared to strongly alkaline solutions such as NaOH. |
| Databáze: | OpenAIRE |
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