Deep Desulfurization of Gasoline by Selective Adsorption over Nickel-Based Adsorbent for Fuel Cell Applications

Autor:	Chunshan Song, Michael J. Sprague, Xiaoliang Ma
Rok vydání:	2005
Předmět:	Olefin fiber Chemistry General Chemical Engineering chemistry.chemical_element General Chemistry Industrial and Manufacturing Engineering Flue-gas desulfurization Nickel Adsorption Chemical engineering Selective adsorption Gasoline Selectivity Ambient pressure
Zdroj:	Industrial & Engineering Chemistry Research. 44:5768-5775
ISSN:	1520-5045 0888-5885
DOI:	10.1021/ie0492810
Popis:	Adsorptive desulfurization of model gasoline fuels and a real gasoline over a nickel-based adsorbent Ni−Al was conducted in a flowing adsorption system at a temperature range of 25−200 °C under ambient pressure without using H2 gas in order to evaluate the desulfurization performance of the adsorbent for producing ultra-low-sulfur gasoline for fuel cell applications. Adsorptive capacity and selectivity of the Ni−Al adsorbent for various sulfur compounds and the effects of coexisting olefin in gasoline as well as adsorptive conditions on the adsorptive performance were examined. It was found that the nickel-based adsorbent shows high capacity and selectivity for the adsorptive desulfurization of gasoline. Olefins in gasoline have a strong inhibiting effect on the desulfurization performance of the nickel-based adsorbent at room temperature. Increasing the temperature to 200 °C can significantly improve the desulfurization performance of the nickel-based adsorbent for real gasoline. The adsorption mechanism...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3eb64c7564b7a0f9e1bdb41ecb8707af https://doi.org/10.1021/ie0492810 Zobrazit plný text záznamu