On the distinction between radical chemistry and Gif chemistry

Autor: Franck Launay, Frances Smith, Valérie N. Le Gloahec, Tingsheng Li, Derek H. R. Barton
Rok vydání: 1997
Předmět:
Zdroj: Tetrahedron Letters. 38:8491-8494
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)10308-2
Popis: Normalized data for cyclooctane and for cyclododecane are compared with cyclohexane as unity. In radical chemistry cyclooctane is 2–3 times more reactive per hydrogen, whereas in Gif chemistry cyclohexane is more reactive than cyclooctane or cyclododecane. Thus by simple competitive experiments a distinction between radical chemistry and Gif chemistry can be made.
Databáze: OpenAIRE