Absorberentwurf für Anlagen zur Behandlung von sauren Erdgasen: Einfluss Prozessparameter auf Betriebsführung und Prozesswirtschaftlichkeit
Autor: | Klaas R. Westerterp, B. Kamphuis, W.P.M. van Swaaij, P. M. M. Blauwhoff |
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Rok vydání: | 1985 |
Předmět: |
business.industry
Chemistry Process Chemistry and Technology General Chemical Engineering Energy Engineering and Power Technology Mechanical engineering General Chemistry Claus process Industrial and Manufacturing Engineering Volumetric flow rate Tray Chemical engineering Natural gas Mass transfer Regenerative heat exchanger Sour gas Absorption (electromagnetic radiation) business |
Zdroj: | Chemical Engineering and Processing: Process Intensification. 19:1-25 |
ISSN: | 0255-2701 |
DOI: | 10.1016/0255-2701(85)80001-5 |
Popis: | Two models of absorber have been developed which describe the absorption of H2S and CO2 from natural gases by aqueous di-isopropanolamine (DIPA) or methyl-di-ethanolamine (MDEA) solutions. In these models mass transfer, reaction and equilibrium processes as they prevail in conventional tray absorbers and in cascades of trickle bed reactors are incorporated. Owing to the better mass transfer characteristics of the latter type of absorber, i.e. the larger ratio between the gas phase and liquid phase mass transfer coefficients, kg/kl, higher selectivities for the absorption of H2S from sour natural gases are realized. The influence of variation of a number of operation and design parameters on tray absorber performance, H2S selectivity and solvent flowrate is demonstrated. The economics of the above type of absorbers together with a solvent regenerator, sulfur recovery unit and tail-gas unit are explained in detail. From the point of view of the economics trickle bed absorbers are very attractive owing to lower investment costs and higher selectivities, which result in lower operating costs than for tray absorbers under identical conditions. |
Databáze: | OpenAIRE |
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