Ring-Closing Metathesis of Titanium–Carbene Complexes Prepared from Thioacetals Having a Carbon–Carbon Double Bond

Autor:	Tooru Fujiwara, Yoshiko Kato, Takeshi Takeda
Rok vydání:	2000
Předmět:	chemistry.chemical_classification Double bond Chemistry Organic Chemistry Thioacetal Reinforced carbon–carbon chemistry.chemical_element Metathesis Biochemistry chemistry.chemical_compound Ring-closing metathesis Drug Discovery Polymer chemistry Carbene Titanium
Zdroj:	Tetrahedron. 56:4859-4869
ISSN:	0040-4020
DOI:	10.1016/s0040-4020(00)00201-5
Popis:	The ring-closing metathesis proceeded to give cycloalkenes in good yields when diphenyl thioacetals having a carbon–carbon double bond were treated with the low-valent titanium species Cp2Ti[P(OEt)3]2 in THF at room temperature and then at reflux. This methodology is successfully applied to the preparation of cyclic ethers and sulfides.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3e984f6f195faaae8469082a4f97b06c https://doi.org/10.1016/s0040-4020(00)00201-5 Zobrazit plný text záznamu Full Text from ScienceDirect