ChemInform Abstract: Synthesis of New Optically Active Sulfoxides with Chelating Properties

Autor:	Kai U. Baldenius, Henri B. Kagan
Rok vydání:	2010
Předmět:	chemistry.chemical_classification Primary (chemistry) Sulfide Quinoline Condensation chemistry.chemical_element General Medicine Optically active Tautomer chemistry.chemical_compound chemistry Polymer chemistry Chelation Titanium
Zdroj:	ChemInform. 22
ISSN:	0931-7597
Popis:	Access to enantiomerically pure 2-pyridinylmethyl sulfoxides and β-imino sulfoxides was sought. The latter were obtained in tautomeric mixtures with their enamines by condensation of optically active β-keto sulfoxides with primary amines. 2-Pyridinylmethyl sulfoxides were synthesized by sulfinate substitution. Titanium catalysed oxidation gave good results for the synthesis of (+)-8-(methylsulfinyl)quinoline from the corresponding sulfide.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3e97654a84d64ddb2ecb9a83d74feae6 https://doi.org/10.1002/chin.199101086 Zobrazit plný text záznamu Plný text