Organosulfur oxidation by hydrogen peroxide using a dinuclear Mn-1,4,7-trimethyl-1,4,7-triazacyclononane complex

Autor:	Jane Murray, Terry R. Lowdon, John R. Lindsay Smith, Paul H. Walton
Rok vydání:	2006
Předmět:	chemistry.chemical_classification Oxygen transfer Sulfide Organic Chemistry chemistry.chemical_element Sulfoxide Manganese Photochemistry Biochemistry Catalysis chemistry.chemical_compound chemistry Drug Discovery Selectivity Hydrogen peroxide Organosulfur compounds
Zdroj:	Tetrahedron Letters. 47:2005-2008
ISSN:	0040-4039
DOI:	10.1016/j.tetlet.2006.01.054
Popis:	A mechanistic study of organosulfide oxidation by H 2 O 2 , using a dinuclear manganese complex as the catalyst, has revealed an unusual switch in the philicity of the oxidant for the first and the second oxygen transfer steps; this switch has been exploited to tune selectivity for each of the products.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3e96ce956793da9115d82df259acb6e8 https://doi.org/10.1016/j.tetlet.2006.01.054 Zobrazit plný text záznamu Full Text from ScienceDirect