Crystal Lattice Control of Unimolecular Photo-Rearrangements. Medium-Dependent Photochemistry of Cyclohexenones

Autor: Trevor J. Greenhough, John R. Scheffer, James Trotter, Wolfgang K. Appel, Anthony S. Secco, Z. Q. Jiang, Leueen Walsh
Rok vydání: 1983
Předmět:
Zdroj: Molecular Crystals and Liquid Crystals. 93:1-15
ISSN: 0026-8941
Popis: The solid state and solution photochemistry of nine compounds possessing the basic cis-4a,5,8,8a-tetra-hydronaphthoquin-1-one-4-ol structure are reported. Two main points are addressed: (1) The reasons for the differences observed between the solution and solid state results, and (2) the source of the solid state reactivity differences among the nine substrates studied.
Databáze: OpenAIRE