ChemInform Abstract: Enantiospecific Synthesis and Allylation of All-Carbon-Substituted α-Chiral Allylic Stannanes

Autor:	Martin Oestreich, Eric S. Schmidtmann
Rok vydání:	2009
Předmět:	Allylic rearrangement Chemistry Reagent Organic chemistry chemistry.chemical_element General Medicine Zinc Lewis acids and bases Carbon
Zdroj:	ChemInform. 40
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200942016
Popis:	Once difficult to obtain, the title compounds can be prepared in virtually enantiomerically pure form with a bis(triorganostannyl) zinc reagent (see scheme). Subsequent diastereoselective thermal (left) and Lewis acid promoted reactions (right) illustrate the synthetic potential of these compounds.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3e84f21577f2557f84e6775216e54c19 https://doi.org/10.1002/chin.200942016 Zobrazit plný text záznamu Plný text