p-Cymene Ruthenium Halide Complexes with a Heterocyclic Carbene
| Autor: | I. V. Skabitskii, S. S. Shapovalov, Sergey G. Sakharov, A. A. Pasynskii, O. G. Tikhonova |
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| Rok vydání: | 2018 |
| Předmět: |
chemistry.chemical_classification
p-Cymene General Chemical Engineering Iodide Halide chemistry.chemical_element General Chemistry 010402 general chemistry 010403 inorganic & nuclear chemistry 01 natural sciences Medicinal chemistry 0104 chemical sciences Ruthenium chemistry.chemical_compound chemistry Anhydrous Ionic compound Acetonitrile Carbene |
| Zdroj: | Russian Journal of Coordination Chemistry. 44:709-715 |
| ISSN: | 1608-3318 1070-3284 |
| DOI: | 10.1134/s1070328418120096 |
| Popis: | The reaction of (p-cymene)Ru(Me2Im)Cl2 with excess Me2ImCO2 in acetonitrile in the presence of NH4PF6 afforded the amino complex [(p-cymene)Ru(Me2Im)(NH3)Cl]PF6. The reaction of (p‑cymene)Ru(Me2Im)Cl2 with excess anhydrous SnCl2 gave the complex (p-cy-mene)-Ru(Me2Im)Cl(SnCl3), whereas treatment of dimeric iodide complex [(p-cymene)RuI2]2 with Me2ImCO2 in acetonitrile gave the ionic compound [Me2ImH][(p-cymene)RuI3]. CIF files: CCDC nos. 1841649 (I), 1841650 (II), 1841648 (III). |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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