Wittig and horner-wittig coupling reactions of 2-substituted cyclic ethers and their application to spiroketal synthesis

Autor:	Helen M. Organ, Anne Wonnacott, Barry Lygo, Steven V. Ley
Rok vydání:	1985
Předmět:	chemistry.chemical_classification Chemistry Organic Chemistry Tetrahydropyran Biochemistry Enol Coupling reaction chemistry.chemical_compound Paravespula vulgaris Drug Discovery Wittig reaction Enol ether Organic chemistry Tetrahydrofuran
Zdroj:	Tetrahedron. 41:3825-3836
ISSN:	0040-4020
Popis:	Wittig and Horner-Wittig coupling reactions of tetrahydropyran or tetrahydrofuran 2-triphenylphosphonium salts or 2-diphenylphosphine oxides with aldehydes and lactols affords good yields of the corresponding enol ethers. In selected examples these enol ether products may be further converted to spiroketals some of which are natural pheromones derived from Dacus oleae and Paravespula vulgaris .
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3e6d0f01bbf2db1c0cb12d4aaa4b4119 https://doi.org/10.1016/s0040-4020(01)91403-6 Zobrazit plný text záznamu