C60 fullerene as carbon source for diamond synthesis

Autor:	Andre Rassat, C. Bogicevic, Claude Fabre, G. Bocquillon
Rok vydání:	1993
Předmět:	Fullerene Alloy General Engineering Analytical chemistry chemistry.chemical_element Diamond engineering.material Nickel chemistry Transition metal X-ray crystallography engineering Graphite Physical and Theoretical Chemistry Carbon
Zdroj:	The Journal of Physical Chemistry. 97:12924-12927
ISSN:	1541-5740 0022-3654
DOI:	10.1021/j100151a047
Popis:	The C[sub 60] fullerene was used as the carbon source to carry out the catalyzed synthesis of diamond, at 6.7 GPa and temperatures between 1200 and 1850[degrees]C; the catalysts used were Ni, Co, and a Co alloy. Under these conditions, the graphite used as the carbon source gave a diamond yield of about 90%; the yield with C[sub 60] depended on the catalyst. With Co, about the same quantity of diamond was obtained from C[sub 60] as from graphite, whereas almost no diamond was synthesized when pure C[sub 60] was used as the carbon source with Ni and the Co alloy as catalysts. The diamond yield recovered to a high level with these two catalysts when a small quantity (about 10%) of graphite was added to the C[sub 60] fullerene. This effect of the addition of graphite to a non-graphite carbon in the synthesis of diamond is different from that observed with amorphous carbons. In all these experiments under high pressure and high temperature with Ni, Co, or Co alloy, the C[sub 60] fullerene was destroyed and transformed into diamond, graphite, or poorly crystallized carbon. 27 refs., 2 figs., 1 tab.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3e5eba94af4861c427fde1f6aa92a1bf https://doi.org/10.1021/j100151a047 Zobrazit plný text záznamu