Thermal Effect on the Distribution of Regular Sterane and Geological Significance

Autor: Min Zhang, Julin Chen, Yunfei Yang, Xiaohui Chen
Rok vydání: 2017
Předmět:
Zdroj: Open Journal of Yangtze Oil and Gas. :249-259
ISSN: 2473-1900
2473-1889
DOI: 10.4236/ojogas.2017.24020
Popis: In order to study thermal effect on distribution characteristics of regular sterane in humic coals, a suit of 25 coals derived from Kuqa Depression in Tarim Basin and Ordos Basin are studied to investigate the distribution of regular sterane in different maturity, which mainly discusses the thermal effect. The results show that the C27ααα/C29ααα regular sterane ratio has a linear relationship with Ro (tmax) and aromatic hydrocarbon maturity parameters in the coals from mature to high-mature stage. It suggests that the distribution of the C27, C29regular steranes will fail to reflect original source input in high evolutionary stage. On the basis of thermal simulation experiment results, it further proves that the distribution patterns result from the demethylation effect of C29 sterane in the mature to high mature evolution stage and the C27ααα/C29ααα regular sterane increases with increasing maturity. The breakage of C-C key in branched chain from C27, C29 regular steranes to make C27ααα/C29ααα regular sterane ratio invariance at high and over mature stage. Therefore, the ratio can be used to distinguish the maturity in high and over mature stage.
Databáze: OpenAIRE