New insights into the mechanism of synergetic photoredox/copper(i)-catalyzed carbocyanation of 1,3-dienes: a DFT study

Autor:	Yanhong Liu, Aili Feng, Rongxiu Zhu, Dongju Zhang
Rok vydání:	2023
Předmět:	General Chemistry
Zdroj:	Chemical Science. 14:4580-4588
ISSN:	2041-6539 2041-6520
DOI:	10.1039/d3sc00002h
Popis:	DFT calculations shows an unexpected mechanism in the photoredox/copper-catalyzed carbocyanation of 1,3-diene, which involves CuI-only catalysis and the single electron transfer from the allyl radical to the oxidized photocatalyst.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3e57c69dc016c398b8cecf69b33f575d https://doi.org/10.1039/d3sc00002h Zobrazit plný text záznamu