Reactions of aza- and diazaanthraquinone N-oxides

Autor: Modesta Espada, Carmen Avendaño, Blanca Ocaña
Rok vydání: 1995
Předmět:
Zdroj: Tetrahedron. 51:1253-1258
ISSN: 0040-4020
DOI: 10.1016/0040-4020(94)01003-i
Popis: 1-Azaanthracene-2,5,8-triones and 1,8-diazaanthracene-2,7,9,10-tetraones, which are structurally related to diazaquinomycin, are prepared by functionalization of azaathraquinone N-oxides. The complete procedure implies a Diels-Alder reaction as a key step, followed by N-oxidation and treatment of the N-oxides with benzoyl or tosyl chlorides in the presence of water.
Databáze: OpenAIRE