Isotopic exchange in the ethanol synthesis from carbon monoxide + molecular hydrogen. Comments on papers by A. Takeuchi and J. R. Katzer
| Autor: | Gisela Henrici-Olivé, Salvador Olivé |
|---|---|
| Rok vydání: | 1984 |
| Předmět: |
chemistry.chemical_classification
Inorganic chemistry General Engineering chemistry.chemical_element Medicinal chemistry Oxygen Dissociation (chemistry) Catalysis Rhodium chemistry.chemical_compound chemistry Methanation Compounds of carbon Methanol Physical and Theoretical Chemistry Carbon monoxide |
| Zdroj: | The Journal of Physical Chemistry. 88:2426-2426 |
| ISSN: | 1541-5740 0022-3654 |
| DOI: | 10.1021/j150655a050 |
| Popis: | Results of papers previously published by Takeuchi and Katzer suggesting mechanisms for the methanol and ethanol synthesis via CO hydrogenation without dissociation in the presence of supported Rh catalysts are not questioned. However, an alternate pathway for the oxygen scrambling at the C/sub 2/ level and an interpretation of the small, but significant, changes in the isotopic distribution of CO in the gas phase are presented. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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