ChemInform Abstract: Grafting of Ru(III) Complex onto Nanosilica and Its Implication as Heterogeneous Catalyst for Aerobic Oxidative Hydroxylation of Arylboronic Acids

Autor: Pradip K. Gogoi, Geetika Borah, Utpal Bora, Nibedita Gogoi
Rok vydání: 2016
Předmět:
Zdroj: ChemInform. 47
ISSN: 0931-7597
DOI: 10.1002/chin.201650060
Popis: An ecofriendly and highly efficient protocol for aerobic oxidative hydroxylation of aryl and heteroaryl boronic acids catalyzed by Ru(III) imine complex immobilized on nanosilica, derived from rice husk, has been developed. The main significance of this protocol is the base free and aerobic reaction condition at room temperature, short reaction time, aqueous reaction medium, and excellent yield of the product. This heterogeneous catalyst is reusable up to sixth cycle without loss in activity.
Databáze: OpenAIRE